產品介紹∣三電極電池測試單元—壓縮控制
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三電極電池測試單元—壓縮控制
THREE ELECTRODE BATTERY TEST CELL – COMPRESSION CONTROLLED

【Redox.me】電化學周邊耗材 電池和超級電容器

三電極電池測試單元—壓縮控制

簡介

CO-3EBATTC_CC-18

  • 該電池被設計為 Swagelok 型結構的高品質替代品,用於對電池和超級電容器材料進行可重複的電化學測量。
  • 該電池由兩個主要元件組成:
    • (i)帶有螺旋測微器螺絲和壓縮彈簧的電池底座,可以精確控制施加到電極夾層上的壓力;
    • (ii)放置陽極、陰極和參考電極的電極盒。
  • (標準) 電極盒和柱塞是為直徑為18 mm,總夾層厚度為2.5 mm的平面電極設計。

我要諮詢

可選擇電解質種類:

  • 有機電解質 
  • 水性電解質 

可選擇電極直徑:

  • 18mm (標準)
  • 12mm
  • 15mm
  • 16mm

介紹

  • 該電池被設計為 Swagelok 型結構的高品質替代品,用於對電池和超級電容器材料進行可重複的電化學測量。
  • 該電池由兩個主要元件組成:
    • (i)帶有螺旋測微器螺絲和壓縮彈簧的電池底座,可以精確控制施加到電極夾層上的壓力;
    • (ii)放置陽極、陰極和參考電極的電極盒。
  • (標準) 電極盒和柱塞是為直徑為18 mm,總夾層厚度為2.5 mm的平面電極設計。
  • 隔板的直徑應至少比電極直徑大 2 mm(最大 22 mm)。鎖環將隔板固定在電極盒中,使電極的插入更加容易和安全,同時確保准確對準。
  • 上、下電極柱塞有多種材料可供選擇:316L不銹鋼(標準)、銅、鋁、鎳等。
  • 針式參考電極從電極盒的側面安裝。由於針腳末端有尖銳的邊緣孔,參考電極(Li/Na/K等)可以很容易地從金屬箔上打孔下來,直接裝入電池。
  • 磁性安裝座有助於快速組裝到電池底座中。施加到電極上的力最高可達 90N,並可通過螺旋測微器控制旋鈕進行調節。
  • 對於雙電極測量,可以使用參考電極沖頭封閉參考電極饋通孔。
  • 電池元件是用對樣品有惰性的材料(不銹鋼和PEEK)製成的。它很適合水性(FKM和EPDM O形環)和有機溶劑(FFKM O形環)的電解質要求。鍍金針腳可確保良好的電氣接觸。該結構是氣密性的,可以毫不費力地在手套箱中進行組裝,將可能的人為錯誤降到最低。

應用說明

該電池可用於所有常見的電池測量,如恒電流循環、循環伏安法或電化學阻抗頻譜。液體和固態或凝膠聚合物的電解質都可以被研究。此外,還可以研究超級電容器材料的特性和性能。可以檢查各種材料,包括典型的鋰離子電極(石墨、NMC、LTO等)和其它化學材料—鈉、鎂、鉀…。它還可以應用於測量隔板和電解質的離子電導率。由於有螺旋測微器的控制旋鈕,可以研究施加在電池上的初始壓力與固態電解質或高容量負極材料技術(無負極(Anode-free)電池)的性能之間的關係。

上圖顯示了施加到電極堆的壓力與從接觸點移動的距離之間的關係。接觸點可以通過檢查 OCV(參見以下影片)或通過計算來確定。要計算接觸點,請從 4 mm 中減去電極堆疊厚度。例如,對於 0.9 mm的堆疊,接觸點(即螺旋測微器螺絲上的數值)將為 4 mm—0.9 mm = 3.1 mm。因此,您應該把螺旋測微器的螺絲調到3.1 mm,從這一點開始測量距離/壓力關係。

技術規格

  • 推薦電極直徑:18 mm(其他選項:12 mm、15 mm、16 mm)
  • 推薦最小隔板直徑:電極直徑+2 mm(最大22 mm)
  • 最大電極夾層厚度:2.5 mm
  • 彈簧係數:10.86 N/mm
  • 最大彈簧荷重:90 N
  • 工作溫度:-40°C – 80°C 

產品包括

  • 1 x 電池底座
  • 1 x 壓縮控制單元
  • 1 x 三電極盒
  • 1 x 參考電極沖頭
  • 1 x上電極柱塞(不銹鋼)
  • 1 x下電極柱塞(不銹鋼)
  • 1 x 隔板鎖環
  • 1 x 鍍金活塞
  • 1 x 壓縮彈簧
  • 2 x 鍍金接觸針腳
  • 1 x O形環 
  • 1 x 3 條導線 ( 1 mm至 4 mm香蕉插頭 )
  • 1 x電極柱塞拆卸工具

Select electrolyte type:

  • organic electrolyte
  • water-based electrolyte

Select elelctrode diameter:

  • 18 mm(default)
  • 12 mm
  • 15 mm
  • 16 mm

description

This cell is designed as high-quality alternative to Swagelok-type constructions for reproducible electrochemical measurements of battery and supercapacitor materials. The cell consists of two main elements: (i) the cell base with micrometre screw and compression spring, which allows precise control of pressure applied to the electrode sandwich; and (ii) electrode cartridge where the anode, cathode and reference electrode are located. The (default) electrode cartridge and plungers are designed for planar electrodes with diameter of 18 mm and total sandwich thickness of 2.5 mm. The diameter of separator shall be at least 2 mm larger than electrode diameter (max. 22 mm). The lock ring secures the separator in the electrode cartridge allowing easy and safe electrodes insertion, while ensuring accurate alignment. The upper and lower electrode plungers are available in various materials: 316L Stainless Steel (default), copper, aluminum, nickel etc. The pin-type reference electrode is installed from the side of the electrode cartridge. Thanks to sharp edged hole at the end of the pin the reference electrode (Li/Na/K etc.) can be easily punched from the metal foil and directly loaded into cell. The magnetic mount facilitates rapid assembly of the cartridge in the cell base. The force applied to the electrodes can reach up to 90N and is adjusted with the micrometer control knob. For 2-electrode measurements the reference electrode feedthrough hole can be closed with the reference electrode punch.

The cell elements are constructed with materials that are inert to the sample (Stainless steel and PEEK). It well fits aqueous (FKM and EPDM O-Rings) and organic solvent (FFKM O-Rings) electrolyte requirements. Good electrical contact is ensured by gold plated pins. The construction is gas-tight and can be effortlessly assembled in the glove box, reducing possible human error to minimum.

Application note 
This cell can be used for all common battery measurements, such as galvanostatic cycling, cyclic voltammetry or electrochemical impedance spectroscopy. Both liquid and solid-state or gel-polymer electrolytes can be studied. Additionally, properties and performance of supercapacitor materials can be investigated. Various materials can be examined, including typical Li-ion electrodes (graphite, NMC, LTO etc.) and other chemistries – sodium, magnesium, potassium etc. It can also be applied to measure the ionic conductivity of separators and electrolytes. Owing to the micrometer control knob, the relationship between the initial pressure applied to the cell and the performance of solid-state electrolytes or metal plating process (anode-free systems) can be studied.

The above graph shows relation of pressure applied to electrode stack and distance travelled from the point of contact. The point of contact can be determined by checking OCV (see manual video) or by calculation. To calculate the point of contact, subtract electrode stack thickness from 4 mm. For example, for the 0.9 mm stack, the point of contact (i.e. reading on micrometer screw) will be 4 mm – 0.9 mm = 3.1 mm. Therefore, you should set micrometer screw to 3.1 mm and measure distance/pressure relation from this point.

Specification 

  • recommended electrode diameter: 18 mm (other options: 12 mm, 15 mm, 16 mm)
  • recommended minimum separator diameter: electrode diameter + 2 mm (max. 22 mm)
  • maximum electrode sandwich thickness: 2.5 mm
  • spring rate: 10.86 N/mm
  • maximum spring load: 90 N
  • operating temperature: -40°C – 80°C (default)

Product includes

  • 1 x cell base
  • 1 x compression control unit
  • 1 x Three-Electrode Cartridge
  • 1 x reference electrode punch
  • 1 x upper plunger (Stainless Steel)
  • 1 x lower plunger (Stainless Steel)
  • 1 x separator locking ring
  • 1 x gold plated piston
  • 1 x compression spring
  • 2 x gold plated pin contact
  • 1 x set of O-rings
  • 1 x set of 3 cable adapters 1mm to 4mm banana plug
  • 1 x electrode plunger removal tool